Spinodal Decomposition in Binary Critical Fluids

Three-dimensional lattice-Boltzmann simulations of critical spinodal decomposition in binary immiscible fluids.

We use a modified Shan-Chen, noiseless lattice-BGK model for binary immiscible, incompressible, athermal fluids in three dimensions to simulate the coarsening of domains following a deep quench below the spinodal point from a symmetric and homogeneous mixture into a two-phase configuration. The model is derivable from a continuous-time Boltzmann-BGK equation in the presence of an intercomponent...

Spinodal Decomposition in Binary Gases

We carried out three-dimensional simulations, with about 1.4 × 10 particles, of phase segregation in a low density binary fluid mixture, described mesoscopically by energy and momentum conserving Boltzmann-Vlasov equations. Using a combination of Direct Simulation Monte Carlo(DSMC) for the short range collisions and a version of Particle-In-Cell(PIC) evolution for the smooth long range interact...

Spinodal decomposition of chemically reactive binary mixtures.

We simulate the influence of a reversible isomerization reaction on the phase segregation process occurring after spinodal decomposition of a deeply quenched regular binary mixture, restricting attention to systems wherein material transport occurs solely by diffusion. Our theoretical approach follows a diffuse-interface model of partially miscible binary mixtures wherein the coupling between r...

Molecular Dynamics Simulation of Spinodal Decomposition in Three-Dimensional Binary Fluids.

Spinodal decomposition of asymmetric binary fluids in a micro-Couette geometry simulated with molecular dynamics.

The spinodal decomposition of quenched polymer/solvent and liquid-crystal/solvent mixtures in a miniature Taylor-Couette cell has been simulated by molecular dynamics. Three stacking motifs, each reflecting the geometry and symmetry of the cell, are most abundant among the fully phase separated stationary states. At zero or low angular velocity of the inner cylindrical drum, the two segregated ...